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ACP - Special IssueRadical chemistry over sunlit snow: interactions between HOx and halogen chemistry at Summit, Greenland Editor(s): J. Dibb, J. Kaiser, J. Stutz, R. von Glasow, and J. AbbattMore Information Overview Paper Active radical chemistry has been observed in the air above sunlit snow surfaces. Past observations of hydroxyl radicals in Greenland showed evidence of unrecognized chemical processes leading to OH concentrations different from those predicted in constrained box models. To investigate if halogen chemistry could explain the observations of unusual hydroxyl radical levels the Greenland Halogen and Hydrogen Radical Photochemistry Experiment (GSHOX) was performed at Summit Greenland in the Summers of 2007 and 2008.
In this special section the following results of the GSHOX experiment will be presented.
- Meteorological and radiative conditions that impact atmospheric chemistry at Summit.
- Direct evidence for the presence of reactive bromine.
- Indirect evidence of halogen chemistry through hydrocarbon clock.
- Sources of bromine and bromide on the Greenland ice sheet.
- Impact of halogen chemistry on OH/HO2 chemistry.
- Impact of halogen chemistry on mercury chemistry.
- NOx and bromine chemistry in the firn.
- Influence of firn chemistry on atmospheric chemistry.
Download citations of all papers: Bromide and other ions in the snow, firn air, and atmospheric boundary layer at Summit during GSHOX J. E. Dibb, L. D. Ziemba, J. Luxford, and P. Beckman Atmos. Chem. Phys., 10, 9931-9942, 2010 Abstract Final Revised Paper (PDF, 521 KB) Discussion Paper (ACPD)
| | 20 Oct 2010 | Modeling chemistry in and above snow at Summit, Greenland – Part 1: Model description and results J. L. Thomas, J. Stutz, B. Lefer, L. G. Huey, K. Toyota, J. E. Dibb, and R. von Glasow Atmos. Chem. Phys., 11, 4899-4914, 2011 Abstract Final Revised Paper (PDF, 1235 KB) Supplement (839 KB) Discussion Paper (ACPD)
| | 26 May 2011 | Temperature and sunlight controls of mercury oxidation and deposition atop the Greenland ice sheet S. Brooks, C. Moore, D. Lew, B. Lefer, G. Huey, and D. Tanner Atmos. Chem. Phys., 11, 8295-8306, 2011 Abstract Final Revised Paper (PDF, 780 KB) Discussion Paper (ACPD)
| | 15 Aug 2011 | Observations of hydroxyl and peroxy radicals and the impact of BrO at Summit, Greenland in 2007 and 2008 J. Liao, L. G. Huey, D. J. Tanner, N. Brough, S. Brooks, J. E. Dibb, J. Stutz, J. L. Thomas, B. Lefer, C. Haman, and K. Gorham Atmos. Chem. Phys., 11, 8577-8591, 2011 Abstract Final Revised Paper (PDF, 6613 KB) Discussion Paper (ACPD)
| | 23 Aug 2011 | Longpath DOAS observations of surface BrO at Summit, Greenland J. Stutz, J. L. Thomas, S. C. Hurlock, M. Schneider, R. von Glasow, M. Piot, K. Gorham, J. F. Burkhart, L. Ziemba, J. E. Dibb, and B. L. Lefer Atmos. Chem. Phys., 11, 9899-9910, 2011 Abstract Final Revised Paper (PDF, 3819 KB) Discussion Paper (ACPD)
| | 27 Sep 2011 | Modeling chemistry in and above snow at Summit, Greenland – Part 2: Impact of snowpack chemistry on the oxidation capacity of the boundary layer J. L. Thomas, J. E. Dibb, L. G. Huey, J. Liao, D. Tanner, B. Lefer, R. von Glasow, and J. Stutz Atmos. Chem. Phys., 12, 6537-6554, 2012 Abstract Final Revised Paper (PDF, 3309 KB) Supplement (220 KB) Discussion Paper (ACPD)
| | 25 Jul 2012 | Overview of the 2007 and 2008 campaigns conducted as part of the Greenland Summit Halogen-HOx Experiment (GSHOX) J. L. Thomas, J. E. Dibb, J. Stutz, R. von Glasow, S. Brooks, L. G. Huey, and B. Lefer Atmos. Chem. Phys., 12, 10833-10839, 2012 Abstract Final Revised Paper (PDF, 1409 KB) Discussion Paper (ACPD)
| | 16 Nov 2012 |
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