Atmospheric Chemistry and Physics www.atmos-chem-phys.net 1680-7316 1680-7324 9 21 2009 10.5194/acp-9-8309-2009 http://www.atmos-chem-phys.net/9/8309/2009/ http://www.atmos-chem-phys.net/9/8309/2009/acp-9-8309-2009.html http://www.atmos-chem-phys.net/9/8309/2009/acp-9-8309-2009.pdf 8309 8316 2009-11-03 Nitric acid and particulate matter measurements at Athens, Greece, in connection with corrosion studies C. Tzanis C. Varotsos covar@phys.uoa.gr M. Ferm J. Christodoulakis M. N. Assimakopoulos C. Efthymiou Department of Applied Physics, University of Athens, University Campus Bldg. Phys. V, Athens 15784, Greece Swedish Environmental Research Institute Ltd. (IVL) P.O. Box 5302, 400 14 Gothenburg, Sweden For a long time, scientists have been concerned about the effects of air pollution on materials and especially on the monuments of the cultural heritage. The EU funded a project, entitled MULTI-ASSESS, to determine these effects and to develop dose-response functions appropriate for the new multi-pollutant environment. The University of Athens participated in this effort as a targeted field exposure test site. In the present paper, the measurements of the passive samplers, which were exposed during the same period with the samples for corrosion studies, at the Athens station, are presented. The results have shown that only 16.5% of the deposited mass was water soluble. The vertical distribution of passive particle collectors has led to the conclusion that the height of maximum deposition of each ion is different. In addition, a variation of the water-soluble mass to total deposited mass between 8% and 31% was observed. Cartalis, C. and Varotsos, C.: Surface ozone in Athens, Greece, at the beginning and at the end of the 20th-century, Atmos. Environ., 28, 3–8, 1994. Chan, L. Y. and Kwok, W. S.: Vertical dispersion of suspended particulates in urban area of Hong Kong, Atmos. Environ., 34, 4403–4412, 2000. Chandra, S. and Varotsos, C. A.: Recent trends of the total column ozone – implications for the Mediterranean region, Int. J. Remote Sens., 16, 1765–1769, 1995. Cracknell, A. P. and Varotsos, C. A.: The IPCC Fourth Assessment Report and the fiftieth anniversary of Sputnik, Environ. Sci. Pollut. R., 14, 384–387, 2007. Efstathiou, M., Varotsos, C., and Kondratyev, K. Y.: An estimation of the surface solar ultraviolet irradiance during an extreme total ozone minimum, Meteorol. Atmos. Phys.\textbf, 68, 171–176, 1998. EU: Council directive 1999/30/EC relating to limit values for sulphur dioxide, nitrogen dioxide and oxides of nitrogen, particulate matter and lead in ambient air, Official Journal of the European Communities L163/41, 1999. Feretis, E., Theodorakopoulos, P., Varotsos, C., Efstathiou, M., Tzanis, C., Xirou, T., Alexandridou, N., and Aggelou, M.: On the plausible association between environmental conditions and human eye damage, Environ. Sci. Poll. R., 9, 163–165, 2002. Ferm, M.: Use of passive samplers in connection with atmospheric corrosion studies, International Workshop on Atmospheric Corrosion and Weathering Steels, Cartagena de Indias, Colombia, 27 September–1 October 2004, 2004. Ferm, M., De Santis, F. and Varotsos, C.: Nitric acid measurements in connection with corrosion studies, Atmos. Environ., 39, 6664–6672, 2005. Ferm, M., Watt, J., O'Hanlon, S., De Santis, F., and Varotsos, C.: Deposition measurement of particulate matter in connection with corrosion studies, Anal. Bioanal. Chem., 384, 1320–1330, 2006. Friess, U., Monks, P. S., Remedios, J. J., Rozanov, A., Sinreich, R., Wagner, T., and Platt, U.: MAX-DOAS O4 measurements: A new technique to derive information on atmospheric aerosols: 2. Modeling studies, J. Geophys. Res., 111, D14203, doi:10.1029/2005JD006618, 2006. Gernandt, H., Goersdorf, U., Claude, H. and Varotsos, C. A.: Possible impact of polar stratospheric processes on midlatitude vertical ozone distributions, Int. J. Remote Sens., 16, 1839–1850, 1995. Heard, D. E., Read, K. A., Methven, J., Al-Haider, S., Bloss, W. J., Johnson, G. P., Pilling, M. J., Seakins, P. W., Smith, S. C., Sommariva, R., Stanton, J. C., Still, T. J., Ingham, T., Brooks, B., De Leeuw, G., Jackson, A. V., McQuaid, J. B., Morgan, R., Smith, M. H., Carpenter, L. J., Carslaw, N., Hamilton, J., Hopkins, J. R., Lee, J. D., Lewis, A. C., Purvis, R. M., Wevill, D. J., Brough, N., Green, T., Mills, G., Penkett, S. A., Plane, J. M. C., Saiz-Lopez, A., Worton, D., Monks, P. S., Fleming, Z., Rickard, A. R., Alfarra, M. R., Allan, J. D., Bower, K., Coe, H., Cubison, M., Flynn, M., McFiggans, G., Gallagher, M., Norton, E. G., O'Dowd, C. D., Shillito, J., Topping, D., Vaughan, G., Williams, P., Bitter, M., Ball, S. M., Jones, R. L., Povey, I. M., O'Doherty, S., Simmonds, P. G., Allen, A., Kinnersley, R. P., Beddows, D. C. S., Dall'Osto, M., Harrison, R. M., Donovan, R. J., Heal, M. R., Jennings, S. G., Noone, C., and Spain, G.: The North Atlantic Marine Boundary Layer Experiment (NAMBLEX). Overview of the campaign held at Mace Head, Ireland, in summer 2002, Atmos. Chem. Phys., 6, 2241–2272, 2006. Jacovides, C. P., Varotsos, C., Kaltsounides, N. A., Petrakis, M., and Lalas, D. P.: Atmospheric turbidity parameters in the highly polluted site of Athens basin, Renew. Energ., 4, 465–470, 1994. Janhäll, S., Molnar, P., and Hallquist, M.: Vertical distribution of air pollutants at the Gustavii Cathedral in Göteborg, Sweden, Atmos. Environ., 37, 209–217, 2003. Kondratyev, K. Y. and Varotsos, C. A.: Volcanic eruptions and global ozone dynamics, Int. J. Remote Sens., 16, 1887–1895, 1995a. Kondratyev, K. Y. and Varotsos, C. A.: Atmospheric ozone variability in the context of global change, Int. J. Remote Sens., 16, 1851–1881, 1995b. Kondratyev, K. Y. and Varotsos, C. A.: Global total ozone dynamics - Impact on surface solar ultraviolet radiation variability and ecosystems .1. Global ozone dynamics and environmental safety, Environ. Sci. Pollut. R., 3, 153–157, 1996. Kondratyev, K. Y. and Varotsos, C. A.: Global tropospheric ozone dynamics – Part II: Numerical modelling of tropospheric ozone variability - Part I: Tropospheric ozone precursors [ESPR 8 (1) 57-62 (2001)], Environ. Sci. Pollut. R., 8, 113–119, 2001. Kondratyev, K. Y. and Varotsos, C.: Remote sensing and global tropospheric ozone observed dynamics, Int. J. Remote Sens., 23, 159–178, 2002. Kucera, V., Tidblad, J., Kreislova, K., Knotkova, D., Faller, M., Snethlage, R., Yates, T., Henriksen, J., Schreiner, M., Ferm, M., Lefevre, R.-A., and Kobus, J: The UN/ECE ICP Materials multi-pollutants exposure on effects on materials including historic and cultural monuments, in: 7th International Conference on Acid Deposition, Prague, Czech Republic, 12–17 June 2005, Conference Abstracts, Prague, 698, 2005. Methven, J., Arnold, S. R., Stohl, A., Evans, M. J., Avery, M., Law, K, Lewis, A. C., Monks, P. S., Parrish, D. D., Reeves, C. E., Schlager, H., Atlas, E., Blake, D. R., Coe, H., Crosier, J., Flocke, F. M., Holloway, J. S., Hopkins, J. R., McQuaid, J., Purvis, R., Rappengluck, B., Singh, H. B., Watson, N. M., Whalley, L. K., and Williams, P. I.: Establishing Lagrangian connections between observations within air masses crossing the Atlantic during the International Consortium for Atmospheric Research on Transport and Transformation experiment, J. Geophys. Res., 111, D23S62, doi:10.1029/2006JD007540, 2006. Monks, P. S., Salisbury, G., Holland, G., Penkett, S. A., and Ayers, G. P.: A seasonal comparison of ozone photochemistry in the remote marine boundary layer, Atmos. Environ., 34, 2547–2561, 2000. Tidblad, J., Kucera, V., Samie, F.: Model for multipollutant impact and assessment of threshold levels for cultural heritage, Final Report, EU 5FP RTD Project (project home page: http://www.corr-institute.se/MULTI-ASSESS/web/page.aspx?pageid=59189), 2005. Tzanis, C.: Ground-based observations of ozone at Athens, Greece during the solar eclipse of 1999, Int. J. Remote Sens., 26, 3585–3596, 2005. Tzanis, C. and Varotsos, C. A.: Tropospheric aerosol forcing of climate: a case study for the greater area of Greece, Int. J. Remote Sens., 29, 2507–2517, 2008. Tzanis, C., Varotsos, C. and Viras, L.: Impacts of the solar eclipse of 29 March 2006 on the surface ozone concentration, the solar ultraviolet radiation and the meteorological parameters at Athens, Greece, Atmos. Chem. Phys., 8, 425–430, 2008. Varotsos, C.: The southern hemisphere ozone hole split in 2002, Environ. Sci. Pollut. R., 9, 375–376, 2002. Varotsos, C.: Modern computational techniques for environmental data; Application to the global ozone layer, Computational Science – ICCS 2005, PT 3 Book Series: Lecture Notes in Computer Science, 3516, 504–510, 2005a. Varotsos, C.: Airborne measurements of aerosol, ozone, and solar ultraviolet irradiance in the troposphere, J. Geophys. Res.-Atmos., 110, D09202, doi:10.1029/2004JD005397, 2005b. Varotsos, C. A., Efstathiou, M. N., and Kondratyev, K. Y.: Long-term variation in surface ozone and its precursors in Athens, Greece - A forecasting tool, Environ. Sci. Pollut. R., 10, 19–23, 2003. Varotsos, C. and Kirk-Davidoff, D.: Long-memory processes in ozone and temperature variations at the region 60 degrees S–60 degrees N, Atmos. Chem. Phys., 6, 4093–4100, 2006. Varotsos, C., Ondov, J., and Efstathiou, M.: Scaling properties of air pollution in Athens, Greece and Baltimore, Maryland, Atmos. Environ., 39, 4041–4047, 2005a. Varotsos, P. and Alexopoulos, K.: Migration entropy for the bound fluorine motion in alkaline earth fluorides, J. Phys. Chem. Solids, 41, 443–446, 1980a. Varotsos, P. and Alexopoulos, K.: Negative activation volumes of defects in solids, Phys. Rev. B, 21, 4898–4899, 1980b. Varotsos, P. and Alexopoulos, K.: Migration parameters for the bound fluorine motion in alkaline earth fluorides. II, J. Phys. Chem. Solids, 42, 409–410, 1981. Varotsos, P., Alexopoulos, K., and Nomicos, K.: Comments on the pressure variation of the Gibbs energy for bound and unbound defects, Phys. Status Solidi B, 111, 581–590, 1982. Varotsos, P., Eftaxias, K., Lazaridou, M., Antonopoulos, G., Makris, J., and Poliyiannakis, J.: Summary of the five principles suggested by Varotsos et al [1996] and the additional questions raised in this debate, Geophys. Res. Lett., 23, 1449–1452, 1996. Varotsos, P. A., Sarlis, N. V., Tanaka, H. K., and Skordas, E. S.: Some properties of the entropy in the natural time, Phys. Rev. E, 71, 032102, doi:10.1103/PhysRevE.71.032102, 2005b.